I 1669 - 1688 Granduca Dimitrij VII Dimitrevic’
II 1688 - 1730 Granduca Michajl III Dimitrevic’
III 1730 - 1757 Granduca Vasilij IV Michajlovic’
IV 1757 - 1787 Granduca Vasilij V Vasiljevic’
V 1787 - 1821 Granduca Dimitrij VIII Vasiljevic’
VI 1821 - 1861 Granduca Michajl IV Dimitrevic’
VII 1861 - 1913 Granduca Vasilij VI Michajlovic’
VIII 1913 - 1965 Granduca Dimitrij IX Vasiljevic’
IX 1965 - 1986 Granduca Dimitrij X Dimitrevic’
X 1986 - Granduca Alfred Josef Baldacchino