| I | 1669 - 1688 | Granduca Dimitrij VII Dimitrevic’ |
| II | 1688 - 1730 | Granduca Michajl III Dimitrevic’ |
| III | 1730 - 1757 | Granduca Vasilij IV Michajlovic’ |
| IV | 1757 - 1787 | Granduca Vasilij V Vasiljevic’ |
| V | 1787 - 1821 | Granduca Dimitrij VIII Vasiljevic’ |
| VI | 1821 - 1861 | Granduca Michajl IV Dimitrevic’ |
| VII | 1861 - 1913 | Granduca Vasilij VI Michajlovic’ |
| VIII | 1913 - 1965 | Granduca Dimitrij IX Vasiljevic’ |
| IX | 1965 - 1986 | Granduca Dimitrij X Dimitrevic’ |
| X | 1986 - | Granduca Alfred Josef Baldacchino |